4-{2-Methoxy-6-[(4-methylphenyl)iminomethyl]phenoxy}phthalonitrile
نویسندگان
چکیده
In the mol-ecule of the title compound, C(23)H(17)N(3)O(2), the methoxy-phenyl ring is oriented at dihedral angles of 13.34 (12) and 88.83 (12)° with respect to the methyl-phenyl and phthalonitrile rings, respectively; the dihedral angle between methyl-phenyl and phthalonitrile rings is 89.67 (10)°. In the crystal structure, weak inter-molecular C-H⋯N inter-actions link mol-ecules into chains. A weak C-H⋯π inter-action is also found..
منابع مشابه
catena-Poly[[{2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}cadmium(II)]-di-μ2-chlorido-[dimethanolcadmium(II)]-di-μ2-chlorido-[{2-methoxy-6-[(4-methylphenyl)iminomethyl]phenolato}cadmium(II)]-di-μ2-chlorido]
The structure of the title compound, [Cd(3)Cl(6)(C(15)H(15)NO(2))(2)(CH(4)O)(2)](n), is based on a layered zigzag polymeric chain along the c axis. The Cd(II) ions are linked by double chlorine bridges alternating between one CdCl(4)(CH(3)OH)(2) and two CdCl(4)(C(15)H(15)NO(2)) octa-hedral coordination units. Additional intrachain N-H⋯O and O-H⋯Cl hydrogen-bond interactions stabilize this arran...
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In the title compound, C(21)H(12)ClN(3)O, the phenoxy ring makes dihedral angles of 51.42 (5) and 65.01 (6)°, respectively, with the chlorophenyl and phthalonitrile rings. In the crystal structure, the mol-ecules are inter-linked through weak C-H⋯N and C-H⋯π contacts, and π-π stacking inter-actions via crystallographic inversion centres form a three-dimensional network. The distance between the...
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The title compound, [Zn(C(15)H(14)NO(2))(2)], contains a four-coordinate Zn atom located on a twofold rotation axis that exhibits a distorted tetra-hedral geometry by two phenolate O atoms and two azomethine N atoms of the Schiff base 2-methoxy-6-[(4-methyl-phen-yl)imino-meth-yl]phenolate ligands.
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